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Silicon Si (Element 14) of Periodic Table

Silicon Si (Element 14) of Periodic Table

14 Si (Silicon)
Crystalline silicon is very brittle, and has a metallic luster & grayish color.
It is the most abundant electropositive element (lose electrons to form positive ions) in The Earth’s crust.

Silicon is usually tetravalent (makes four bonds to other atoms) in its compounds, although sometimes its bivalent (two or more atoms bound together as a single unitmolecule), and it’s purely electropositive in its chemical behaviour.

Hyperpure Silicon is an intrinsic/naturally semiconductor.

Silicon is a relatively inert element (atoms don’t combine with other atoms), but it is attacked by halogens & dilute alkali.
It doesn’t affect by acids, except hydrofluoric (HF).

The element transmits more than 95% of all wavelengths of infrared, from 1.3 to 6.y micro-m.

It forms various series of hydrides (anion of hydrogen, H), various halides (many of which contain silicon-silicon bounds) and many series of compounds which contain oxygen, which can have ionic or covalent properties.

silicon element

Silicon element

Identity
CAS Number: CAS7440-21-3
CID Number:  CID5461123
DOT Hazard Class:  4.1
DOT Number:  1346
RTECS Number:  RTECSVW0400000

Basic Properties of Silicon

Pronunciation:  Sil-a-kam
Appearance:  Crystalline, reflective with bluish tinged faces
Mass Number:  28
Standard Atomic weight:  28.084, 28.086  g/mol
Atomic number (Z):  14
Electrons: 14
Protons:  14
Neutrons:  14
Period:  3
Group:  14
Block:  p
Element category:  Metalloid (Semi-metal)
Electrons per shell:  K2, L8, M4
Electron configuration:  1s22s22p63s23p2

silicon electron configuration

Silicon Electron Configuration

Thermal Properties of Silicon

Phase:  Solid
Melting point:  1687 K (1414 oC, 2577 oF)
Boiling point:   3538 K (3265 oC, 5909 oF)
Debye temperature:  645 K (701.33 oC, 371.85 oF)
Fusion heat:  50.21 kJ/mol
Vaporization heat:  383 kJ/mol
Specific heat:  710 J/(kg K)
Molar heat capacity:  19.789 J/(mol.K)
Thermal expansion:  2.6 μm/(m∙K)
Thermal conductivity:  149 W/(m∙K)

Electrical properties of Silicon

Electrical conductivity:  1000 S/m
A Electrical resistivity:  2.3×103 Ω∙m
A Electrical type:  Conductor
Band gap:  1.12 eV

Magnetic Properties of Silicon

A Magnetic type:  Diamagnetic
Magnetic susceptibility (xmol):  -3.9×10-6 cm3/mol
Volume magnetic susceptibility:  -0.00000373
Mass magnetic susceptibility:  -1.6×10-9 m3/kg
Molar magnetic susceptibility:  -0045×10-9 m3/mol

Physical Properties of Silicon

Density:  2.33 g/cm3 (In solid)  2.57 g/cm3 (In Liquid at M.P)
Molar volume:  0.000012054 m3/mol
Young’s modulus:  130-185 GPa
Shear modulus:  50-80 GPa
Mohs Hardness:  6.5
Bulk modulus:  97.6 GPa
Poisson ratio:  0.064-0.28
Vicker hardness:  9630 MPa
Sound Speed:  8433 m/s

Atomic Properties of Silicon

Oxidation states:  +4, +3, +2, +1,-1, -2, -3, -4
Valence Electrons:  3s2 3p2
Ionization potential of an atom:  8.12
Ionization energies:  1st: 786.4 kJ.mol 2nd: 1577 kJ/mol 3rd: 3231.5 kJ/mol
Ionic radius:   40 pm
Atomic radius:  111 pm (empirical)
Van der Waals:  210 Pm
Covalent radius:  111 pm
Filling Orbital:  3p2
Crystal structure:  Face centered diamond cubic
Lattice angles:  π/2, π/2, 2π/3
Lattice constant:  543.07, 543.07, 543.07 pm
Grid parameters:  a=5.4307 Å
Space Group Name:  Fd_3m
Space Group Number:  227

Face centered diamond cubic

Face Centered Diamond Cubic (FCDC)

Reactivity of Silicon

Electronegativity:  1.9 (pauling scale)
Valence:  +4
Electron affinity:  133.6 kJ/mol

Nuclear Properties of Silicon

Half Life:  Stable (Infinity) 
Lifetime:  Stable (Infinity)
Quantum Number:  3P0
Neutron cross section (Brans):  0.166
Neutron Mass Absorption:  0.0002
Isotopes:   28Si 29Si 30Si 31Si 32Si

Isotope Abundance (%) Atomic Mass g/mol Half Life (t1/2)
28Si 92.2 27.972 Stable
29Si 4.7 28.975 Stable
30Si 3.1 29.977 Stable
31Si Trace 2.62 h
32Si Trace 153 y

Chemical Reactions of Silicon

Silicon doesn’t react with Air under normal condition:
If silicon is heated above 900o C, it reacts with the oxygen, and forming Silicon dioxide:
Si (s) + O2 (g) → SiO2 (s)
If silicon is heated above 1400o C, it reacts with the nitrogen, and forming Silicon nitrides:
2 Si (s) + N2 (g) → 2 SiN (s)
3 Si (s) + 2 N2 (g) → Si3N4 (s)

Metal Doesn’t reacts with water:

The metal reacts with all Halogens to form Silicon (Vl) halides:
Si (s) + 2 F2 (g) → SiF4 (s)   (Silicon (Vl) fluoride)
Si (s) + 2 Cl2 (g) → SiCl4 (s)   (Silicon (Vl) chloride)
Si (s) + 2 Br2 (g) → SiBr4 (s)   (Silicon (Vl) bromide)
Si (s) + 2 I2 (g)  →  SiI4 (s)      (Silicon (Vl) iodide)

The element doesn’t react with most acids, but dissolved by hydrofluoric acid (HF).
Si (s) + 6 HF (aq) ⇌ [SiF6]2- (aq) + 2H+ (aq) + 2 H2 (g)

Production
Silicon carbide is made by reduction of Quartz sand with excess coke or anthracite at 2000o C-2500o C:
SiO2 + 2 C → Si + 2 CO
Si + C →  SiC
With an excess of SiO2 used to stop Silicon carbide from accumulating:
2 SiC + SiO2 → 3 Si + 2 CO
 
For another reaction, Sometimes used aluminothermal reductionof silicon dioxide (SiO2)
3 SiO2 + 4 Al → 3 Si + 2 Al203

Purify MG-Si into EG-Si by converting Liquid volatile silicon such as Dichlorosilane (SiH2Cl2), Monosilane (SiH4), and Trichlorosilane (SiHCl3).
conversion is done by reacting it with anhydrous hydrogen chloride (HCl) at 300o C in a fluidized bed reactor:
MGS + 3 HCl → SiHCl3 + H2
Now, Boils at room temperature, where impurities can easily be removed through distillation to produce extremely high purity Trichlorosilane (TCS) liquid, which is converted to solid polysilicon by siemens process, that give results in EG-Si with purity of 99.999999998%

Silicon History

Naming:  After Latin ‘silicis’ or ‘silex’ (meaning flint)
Discovery & 1st Isolation:  Jöns Jacob Berzelius (1823)
Named By:  Thomas thomson (1817)

Silicon Uses

Silicon is one of the most useful elements for humankind.
Mostly, it is used to make an alloys including ferro-silicon (iron-silicon) & aluminium-silicon (AlSi) to provide more resistance.
These alloys are used to make engine blocks, dynamo & transformer plates, cylinder heads and machine tools, and to deoxidise steel.

Silicon is also used to make silicones (polysiloxanes), It is a silicon-oxygen synthetic polymer with attached methyl group (contain 1 carbon atom & 3 hydrogen atom, Like CH3).
It can be prepared by hydrolyzing (break down by chemical reaction with water) a silicon organic chloride, such as dimethyl silicon chloride (C2H6Cl2Si).

Silicones are quite stable to extreme temperatures, water, oxidation, and have useful dielectric (electrical insulator), antistick, and antifoam properties.
Silicone oil is a lubricant and is added to hair conditioners & some cosmetics.
Silicone rubber is used as a waterproof sealant in bathrooms, around windows, roofs, and pipes.

Silicone rubber

Silicone Rubber for Sealant Against Water & Air Penetration.

A Silicone is one of the two best materials for making reborn babies or artificial human toys, and the other material is vinyl (-CH=CH2).

silicone doll

Silicone Doll (Artificial Human Toys)

Silica gel is a substance that absorbs moisture from air, which makes these packets perfect for keeping things (such as New purse, shoes, headache medicine etc..) extremely dry & moisture-free.

silica gel

Silica Gel Pack

Silicone grease is a waterproof grease, which is used for lubricating and preserving rubber parts, and also used in plumbing industry in faucets and seals.
It is made by combining a silicone oil (polydimethylsiloxane, (C2H6OS)n) with a thickener (amorphous fumed silica.).

Other uses of silicone are silicone rings, silicone masks, silicone case, silicone sheet, silicone pads, etc..

silicone masks

Realistic Silicone Masks

Silicone case

Silicone Case

silicon rings

Silicon Rings for Male and Female

Electronic grade Silicon (EG-Si, Extremly highly purified) is extensively used as a semiconductor in solid-state devices (a device in which electricity flows through solid semiconductor Like in solar cells (Photovoltaic cells, converting solar energy into electricity), transistors, rectifiers etc..) in the computer, space-age & microelectronics industries.
The silicon can be doped with tiny amounts of gallium, boron, arsenic or phosphorus to control its electrical properties.
Upgraded Metallurgical grade silicon (UMG-Si, slightly Purer of MG-Si) can be used in cheaper electronics devices.
Metallurgical grade silicon (MG-Si, with purity of 98% or higher) is used as raw material in the manufacture of organosilica and silicon resins, oils & seals.  

Granite and most other rocks are complex silicates, which are useful refractory material for high-temperature work, and these are used for civil engineering projects.
Sand (silicon dioxide or silica, SiO2) & Clay (aluminium silicate, Al2SiO5) are used to make concrete, brick, and cement.
Sand (Silica, SiO2) is also the principal ingredient of glass, which has thousands of uses, such as window glass, containers, insulators, sawing stone, grinding, sand blasting, wood paste, in Laboratories, in chemical plants, etc..

Silicon tetrachloride (SiCl4) can be used as iridize glass (a glass is coated with a fine metallic coating).
Silica is one of the most inexpensive (uncostly) materials with excellent thermal, mechanical, electrical, and optical properties.
Due to its good Refractory properties, Silicon (as silicate) is also used in making pottery, enamels and high-temperature ceramics.
 
Silicon carbides (SiC) are important abrasives,which is one of the hardest material and it has been used in lasers to produce coherent light of 4560 Å.

Biological role of Silicon

Silicon is essential to plants (Rice etc..) for their growth, and use in animal cells is uncertain, But there is some evidence that silicon is important to human health for their Bone, Hair, Nail, & Skin tissues.

Phytoliths (plant stone) are tiny particles of silica that form inside some plants.
Since these particles do not decay/rot, they remain in fossils and provide us useful evolutionary evidence.

Silicon is non-toxic but some silicate minerals, such as asbestos, are carcinogenic (promotes the formation of cancer).

Workers, such as stonecutters & miners, who are breathed siliceous rocks dust into large quantities, which can develop a serious Lung disease called silicosis.

Abundance of Silicon

Silicon is the 2nd most abundant element (first is oxygen) in the Earth’s crust (27.7%, by weight), and 7th most abundant in the universe.
It is not found free in nature, but occurs chiefly as Silica (silicon dioxide, SiO2) and as silicates (SiO42-).
It is also a component of Tektites (a rare blacky natural glass formed when an asteroid strikes the Earth).

tektites

Tektites

Natural silicon contains 92.2% of isotope S28, 4.7% of S29 and 3.1% of S30.

Sandstone, Rock crystal, Quartz, Smoky quartz, Amethyst, Onyx, Flint, Opal, Jasper, Heliotrope, Tridymite, Citrine, Agate, Chrysoprase, Tridymite, Cristobalite, Coesite, and Lechatelierite are some of the forms in which the oxide appears
A few of the numerous silicate minerals are Granite, Asbestos, Hornblende, Feldspar, Clay, Mica, etc..

Elemental Silicon is produced commercially by heating silica & carbon in an electric furnace, using carbon electrodes.

Amorphous silicon (a-Si, Non-crystalline form of silicon) can be prepared as a brown powder, which can be easily melted or vaporized.

The Czochralski process is a method of crystal growth, which is commonly used to produce single crystals of silicon used for solid-state or semiconductor devices.

Highly-pure silicon for the electronics industry, is prepared by the thermal decomposition of ultra-pure tetrachlorosilane  or trichlorosilane (HSiCl3) in a hydrogen atmosphere, and by a vacuum float zone process.

Czochralski Process

Czochralski Process

Annual world wide production is around 6,400,000 tonnes.
0.07% (In Universe)
14% (In Meteorites)
0.09% (In Sun)
27% (In Earth’s Crust)
0.0001% (In Oceans)
0.026% (In Humans)

World’s Top producers of Silicon

1) China (80%, 4.5 million tonnes)
2) Russia (610,000 tonnes)
3) Norway (330,000 tonnes)
4) Brazil (240,000 tonnes)
5) United States (170,000 tonnes)
 
Silicon Price  
Pure (99.995%) metal price is around  $170-$190 per KG (KiloGram)

#silicon #silicone

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