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Rhodium Rh (Element 45) of Periodic Table

Rhodium Rh (Element 45) of Periodic Table

45 Rh (Rhodium)
Rhodium is an element of Platinum group metals (PGM) together with ruthenium, palladium, osmium, iridium, and platinum.
Rhodium is the rarest of all non-radioactive metals.
 
Rhodium is a lustrous and silvery white and at red heat slowly changes in air to the sesquioxide(an oxide containing three atoms of oxygen with two atoms of another element eg: Al2O3 , La2O3).
At higher temperatures It turns black to the element.
 
It is unaffected by air and water up to 600 oC, and insoluble in most acids, including Aqua regia (mixture of nitric acid and hydrochloric acid).
But it dissolved in hot concentrated sulfuric acid (H2SO4) and it is attacked by molten alkalis.
 
It has a higher melting point and lower density than platinum, and it is highly reflective, hard, and durable.

Rhodium element

Rhodium element

Palladium

(Precious Metals)Palladium Gold Platinium Silver Rhodium

Identity
CAS Number: CAS7440-16-6
CID Number:  CID23948
DOT Hazard Class:  4.1
DOT Number:  3089
RTECS Number:  RTECSVI9069000

Basic Properties of Rhodium

Pronunciation:  Roh-dee-am
Appearance:  Silvery white Metallic
Mass Number:  103
Standard Atomic weight: 102.905  g/mol
Atomic number (Z):  45
Electrons: 45
Protons:  45
Neutrons:  58
Period:  5
Group: 9
Block:  d
Element category:  Transition metal
Electrons per shell:  K2, L8, M18, N16, O1
Electron configuration:  1s22s22p63s23p63d104s24p64d85s1

Rhodium electron configuration

Rhodium Electron Configuration

Thermal Properties of Rhodium

Phase:  Solid
Melting point:  2237 K (1964 oC, 3567 oF)
Boiling point:   3968 K (3695 oC, 6683 oF)
Debye temperature:  480 K (206.85 oC, 404.33 oF)
Fusion heat:  26.59 kJ/mol
Vaporization heat:  493 kJ/mol
Specific heat:  240 J/(kg K)
Molar heat capacity:  24.98 J/(mol.K)
Thermal expansion:  8.2 μm/(m∙K)
Thermal conductivity:  150 W/(m∙K)

Electrical properties of Rhodium

Electrical conductivity: 23×106 S/m
A Electrical resistivity:  43.3 nΩ∙m
A Electrical type:  Conductor

Magnetic Properties of Rhodium

A Magnetic type:  Paramagnetic
Magnetic susceptibility (xmol):  +111×10-6 cm3/mol
Volume magnetic susceptibility:  0.0001693
Mass magnetic susceptibility:  13.6×10-9 m3/kg
Molar magnetic susceptibility:  1.4×10-9 m3/mol

Physical Properties of Rhodium

Density:  12.41 g/cm3 (In solid)  10.7 g/cm3 (In Liquid at M.P)
Molar volume:  0.0000082655 m3/mol
Young’s modulus:  380 GPa
Shear modulus:  150 GPa
Mohs Hardness:  6.0
Bulk modulus:  275 GPa
Poisson ratio:  0.26
Vicker hardness:  1100-8000 MPa
Brinell hardness:   980-1350 MPa
Sound Speed:  4700 m/s

Atomic Properties of Rhodium 

Oxidation states:  6, 5, 4, 3, 2, 1, -1, -3
Valence Electrons:  4d8 5s1
Ion charge:  Rh3+
The ionization potential of an atom:  7.7
Ionization energies:  1st: 719.7 kJ.mol 2nd: 1740 kJ/mol 3rd: 2997 kJ/mol
Ionic radius:   68 pm
Atomic radius:  empirical: 134 pm
Van der Waals: 195 pm
Covalent radius:  142±7 pm
Filling Orbital:  4d8
Crystal structure:  Face-Centered Cubic
Lattice angles:  π/2, π/2, π/2
Lattice constant:  380.34, 380.34, 380.34 pm
Grid parameters:  a=3.803 Å
Space Group Name:  Fm_3m
Space Group Number:  225

Face Centered Cubic

Face Centered Cubic (FCC)

Reactivity of Rhodium

Electronegativity:  pauling scale: 2.28
Valence:  +6
Electron affinity:  109.7 kJ/mol

Nuclear Properties of Rhodium

Half Life:  Stable (Infinity)
Lifetime:  Stable (Infinity)
Quantum Number:  4F9/2
Neutron cross section (Brans):  145
Neutron Mass Absorption:  0.063
Isotopes:  99Rh 101mRh 101Rh 102mRh 102Rh 103­Rh 105Rh

Isotope Abundance (%) Atomic Mass g/mol Half Life (t1/2)
99Rh Syn 16.1 d
101mRh Syn 4.34 d
101Rh Syn 3.3 y
102mRh Syn 3.7 y
102Rh Syn 207 d
103Rh 100 102.905 Stable
105Rh Syn 35.36 h

Chemical Reactions

Rhodium does not react with air under normal conditions, But If heating with oxygen at 600°C:
4 Rh (s) + 3 O2 (g) → 2 Rh2O3 (s) [dark grey] (Rhodium (III) oxide)

The metal reacts with all Halogens:
reacts directly with fluorine gas to form the highly corrosive,
Rh (s) + 3 F2 (g) → RhF6 (s)  [black]  (rhodium(VI) fluoride, Highly corrosive)
If heated, the hexafluoride is transformed to:
4 RhF6 (s) → [RhF5]4 (s) [dark red] + 2 F2 (g) (tetrameric rhodium(V) fluoride)
Under dry condition:
2 Rh (s) + 3 F2 (g) → 2 RhF3 (s) [red]

2 Rh (s) + 3 Cl2 (g) → 2 RhCl3 (s)  [red]  (Rhodium (lll) chloride)
2 Rh (s) + 3 Br2 (g) → 2 RhBr3 (s)  [red-brown]  (Rhodium (lll) bromide)

The reduction of nitrogen oxides to nitrogen and oxygen
2 NOx → x O2 + N2

Rhodium History

Naming:  Greek: rhodon (rose). Its salts give a rosy solution.
Discovery and First isolation: William Hyde Wollaston (1804) in London

Rhodium Uses

Primary use of Rhodium is as an alloying agent to harden palladium  and platinum.
These alloys are used in furnace windings, pen nibs, thermo coupling elements, headlight reflectors, phonograph needles, bearing, bushings for glass fiber production, electrodes for aircraft spark plugs, and laboratory crucibles.
It is useful as an electrical contact material as it has a low electrical resistance, a low and stable contact resistance, and is highly corrosion resistant.

Rhodium is used in catalytic converters for cars, where it reduces nitrogen oxides (NOX) in exhaust gases.
It is also used for jewelry, for decoration, and as a catalysts in chemical industry for making Nitric acid (HNO3), Acetic acid (CH3COOH) and hydrogenation reactions.

Plated rhodium is produced by electroplating or evaporation, which is exceptionally hard and is used for optical instruments (to coat optical fibers and optical mirrors).

Rhodium Plating

Rhodium Plating

Biological role:  It is a suspected carcinogen. Exposure (contact) to rhodium (metal fume and dust, as Rh) should not exceed 1 mg/m3(8-hour time-weighted average, 40-hour week).

Abundance of Rhodium 

Rhodium occurs uncombined in nature, along with other platinum metals in river sands of North and South America.
It is also found with other platinum metals in the copper-nickel sulfide, area of the Sudbury, Ontario region (Canada).
It is obtained commercially as a by-product of copper and nickel refining.

Annual world wide production is around 30 tons.
0.6×10-7% (In Universe)
1.8×10-5% (In Meteorites)
2×10-7% (In Sun)
7×10-8% (In Earth’s Crust)

World’s Top 3 producers of Rhodium

1) South Africa
2) Russia
3) Zimbabwe

World’s Top 3 Reserve holders of Rhodium

1) South Africa
2) Russia
3) USA

#Rhodium

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