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Magnesium Mg (Element 12) of Periodic Table

12 Mg (Magnesium)

Magnesium

Flashcard of Magnesium

AMagnesium is a very light, shiny silvery-white, and fairly tough metal.

The element is very chemically active, where it takes place of hydrogen in boiling water and a huge amount of metals can be produced by thermic reduction of its salts and oxidized forms with magnesium.

It tarnishes slightly in air, and if magnesium divided finely, than it readily ignites upon heating in air, which burns with a dazzling (very bright) white flame.

It reacts readily with most non-metals and almost every acid.

Magnesium reacts slightly or not at all with most of the alkalis and many organic substances, like hydrocarbons, alcohols, amines, aldehides, phenols, esters and most of the oils. 

Used as a catalyst, magnesium promotes organic reactions of Addition, Condensation, Dehalogenization, and Reduction.

magnesium element

Magnesium Element

Identity
CAS Number: CAS7439-95-4

CID Number:  CID5462224
DOT Hazard Class:  4.1
DOT Number:  2950

Basic Properties of Magnesium

Pronunciation:  mag-nee-zee-am
Appearance:  Shiny grey solid
Mass Number:  24
Standard Atomic weight: 24.304, 24.307 g/mol
Atomic number (Z):  12
Electrons: 12
Protons:  12
Neutrons:  12
Period:  3
Group:  2
Block:  s
Element category:  Alkaline earth metal
Electrons per shell:  K2, L8, M2
Electron configuration:  1s22s22p63s2

magnesium electron configuration

Magnesium Electron Configuration

Thermal Properties of Magnesium

Phase:  Solid
Melting point:  923 K (650 oC, 1202 oF)
Boiling point:   1363 K (1091 oC, 1994 oF)
Debye temperature:  318 K (44.85 oC, 112.73 oF)
Fusion heat:  8.48 kJ/mol
Vaporization heat:  128 kJ/mol
Specific heat:  1020 J/(kg K)
Molar heat capacity:  24.869 J/(mol.K)
Thermal expansion:  24.8 μm/(m∙K)
Thermal conductivity:  156 W/(m∙K)

Electrical properties of Magnesium

Electrical conductivity:  23×106 S/m
A Electrical resistivity:  43.9 nΩ∙m
A Electrical type:  Conductor

Magnetic Properties of Magnesium

A Magnetic type:  Paramagnetic
Magnetic susceptibility (xmol):  +13.1×10-6 cm3/mol
Volume magnetic susceptibility:  0.000012
Mass magnetic susceptibility:  6.9×10-9 m3/kg
Molar magnetic susceptibility:  0.168×10-9 m3/mol

Physical Properties of Magnesium

Density:  1.737 g/cm3 (In solid)  1.585 g/cm3 (In Liquid at M.P)
Molar volume:  0.000013984 m3/mol
Young’s modulus:  45 GPa
Shear modulus:  17 GPa
Mohs Hardness:  1-2.5
Bulk modulus:  36 GPa
Poisson ratio:  0.29
Brinell hardness:  44-260 MPa
Sound Speed:  4940 m/s

Atomic Properties of Magnesium 

Oxidation states:  +2, +1
Valence Electrons:  3s2
Ion charge:  Mg2+
The ionization potential of an atom:  7.61
Ionization energies:  1st: 737.6 kJ.mol 2nd: 1450.6 kJ/mol 3rd: 7732.6 kJ/mol
Ionic radius:   72 pm
Atomic radius:  160 pm (empirical)
Van der Waals:  173 Pm
Covalent radius:  141±7 pm
Filling Orbital:  3s2
Crystal structure:  Hexagonal close packed
Lattice angles:  π/2, π/2, 2π/3
Lattice constant:  320.94, 320.94, 521.08 pm
Grid parameters:  a=0.32094 Å c=0.52 Å
Attitude c/a:  1.624
Space Group Name:  P63/mmc
Space Group Number:  194

Hexagonal Close Packed

Hexagonal Close Packed (HCP)

Reactivity of Magnesium

Electronegativity:  1.31 (pauling scale)
Valence:  2
Electron affinity:  0 kJ/mol

Nuclear Properties of Magnesium

Half Life:  Stable (Infinity)
Lifetime:  Stable (Infinity)
Quantum Number:  1S0
Neutron cross section (Brans):  0.063
Neutron Mass Absorption:  0.0001
Isotopes:   24Mg 25Mg 26Mg

 

Isotope Abundance (%) Atomic Mass g/mol Half Life (t1/2)
24Mg 79 23.984 Stable
25Mg 10 24.985 Stable
26Mg 11 25.982 Stable

Chemical Reactions of Magnesium

The metal reacts with oxygen at room temperature, and forming a passivating layer of MgO, and when Mg ignited, then it reacts with both oxygen & nitrogen forming a mixture of magnesium oxide & Magnesium nitride (Mg3N2):
2 Mg(s) + O2 (g) → 2 MgO (s)
3 Mg (s) + N2 (g) → Mg3N2 (s)

Mg does not react with liquid water at room temperature, but It reacts steam, and forming magnesium hydroxide (Mg(OH)2), with excess steam & hydrogen gas:
Mg (s) + H2O (g) → MgO (aq) + H2 (g)
Mg (s) + 2 H2O (g) → Mg(OH)2 (aq) + H2 (g)

Metal Reacts with
Cl2, and forming magnesium chloride:

Mg (s) + Cl2 (g) → MgCl2 (s)

The metal dissolves readily in acids, and forming Mg (II) ions & Hydrogen:
Mg (s) + H2SO4 (aq) → Mg2+ (aq) + SO42- (aq) + H2 (g)
Mg (s) + 2 HCl (aq) → Mg2+ (aq) + 2 Cl (aq) + H2 (g)

Mg (II) is precipitated by hydroxide ions (OH-), and Ammonia (NH3) will also precipitate Mg (II) as hydroxide, but the precipitation is incomplete:
Mg2+ (aq) + 2 OH (aq) → Mg(OH)2 (s)

Production
To extract the Mg, firstly, calcium hydroxide (Ca(OH)2) is added to seawater to form magnesium hydroxide precipitate:
MgCl2 + Ca(OH)2 → Mg(OH)2 + CaCl2
Brucite (Magnesium hydroxide, Mg(OH)2) is insoluble in water, can be filtered out and reacted with hydrochloric acid (HCl) to produced concentrated magnesium chloride (MgCl2):
Mg(OH)2 + 2 HCl → MgCl2 + 2 H2O
Finaly, magnesium produces by electrolysis of magnesium chloride (MgCl2).

Magnesium History

Naming:  After magnesia, in Greece
Discovery:  Joseph Black (1755)
First Isolation:  Humphry Davy (1808)

Magnesium Uses

Magnesium is 1/3rd less dense than aluminium.
It is used as alloying agent with aluminium to improve mechanical, fabrication and welding characteristics, these alloys are useful in car, missile, and aeroplane construction.

Magnesium is used in products for benefit of being lightweight, such as Laptops, Luggage, Car seats, Cameras, and Power tools, It is also added in molten iron & steel to remove sulfur.
It is used in producing nodular graphite cast iron, and as an additive to conventional propellants.

It is also used as a reducing agent (compound or element that loses an electron) in the production of pure uranium and other metals from their salts.

Magnesium ignites easily in air and burns with a very bright light, that’s why it’s used in flashlight Photography, Pyrotechnics, Fireworks, Flares, Sparklers, and Incendiary Bombs.

burning magnesium

Burning Magnesium (Very Bright Light)

Magnesium sulfate (MgSO4) is sometimes used as a mordant (dye fixative) for dyes.

Magnesium hydroxide
(Mg(OH)2) is added to plastics to make them fire retardant ( to slow or stop the spread of fire or reduce its intensity).

Dead-burned magnesite (Magnesium oxide, MgO) is used as refractory material  to make Heat-resistant bricks for fire places, Furnaces, & Convertors.
It is a mineral supplement which is used to treat or prevent low level of Magnesium, that’s why it is also added in cattle feed & fertilisers.

Magnesium hydroxide (milk of magnesia, Mg(OH)2), magnesium sulfate (Epsom salts, MgSO4), magnesium chloride (MgCl2), and magnesium citrate (C6H6MgO7) are all used in medicine.

Grignard reagents (RMgX, where R: alkyl or aryl and X: Halogens) are organic magnesium compounds that are important for the chemical industry.
It was used for a long time for synthesizing special & complex organic components.

Biological role of Magnesium

Organic Magnesium is very essential element in both plant & animal life.

Chlorophyll (magnesium-centred porphyrin complex, C20H14MgN4) is the chemical that allows plants to capture sunlight, and photosynthesis take place.

Without magnesium, photosynthesis could not take place, result to this plants would not grow, and animals life also would be finished.

Magnesium is essential for humans to the working of hundreds of enzymes (protein molecules in cells).
It is affected various factors like Weight, size etc..

Humans daily intake (Adult) around 240–370 mg (milligrams) of magnesium, and stores around 20 grams in our bodies, mainly in the bones to preventing osteoporosis.
It is also benefits in Diabetes, Heart health, Premenstrual syndrome, Migraine headaches, Healthy bones, Relieving anxiety etc..

It has very low toxicity, and not considered to be hazardous to health, but Inhalation dust may irritate mucous membranes or upper respiratory tract like eyes, skin etc..

Magnesium dust explosion possible if in granular or powder form, mixed with air.

It should be handle with great care, because the substance may spontaneously ignite on contact with air, where it can occur serious fires, especially when finely divided.
Once it catch fire, you can’t extinguish it by water (H2O), CO2, soil (SiO2) and other oxygen compounds, Because burning magnesium catches oxygen atoms and start to burning  again.
For extinguish magnesium fire, oxygen supply should be cut off.

Magnesium Rich Foods

Food Quantity Contain Magnesium
Dark Chocolate 28 grams (1 ounce) 64 Mg
Avocados 1 medium avocado 58 mg
Cashews (Nuts) 28 grams (1 ounce) 80 mg
Almonds (Nuts) 28 grams (1 ounce) 85 mg
Peanut Butter 2 tablespoons 50 mg
Cooked Black Beans (Legumes ) 170 grams (1 Cup) 120 mg
Soymilk 1 Cup 61 mg
Cow’s milk 1 Cup 34 mg
Tofu (Staple food) 100 grams (3.5 ounce) 53 mg
Pumpkin Seeds 28 grams (1 ounce) 150 mg
Dry Roasted Sunflower Seeds 1 Cup 512 mg
Roasted Sesame Seeds 28 grams (1 ounce) 101 mg
Dry Buck Wheat (Whole Grains) 28 grams (1 ounce) 65 mg
Bread (Whole Wheat) 1 Slice 23 mg
Cooked Oatmeal 1 Cup 58 mg
Salmon packs (Fatty Fish) 178 grams (6.4 ounce) 53 mg
Bananas 1 Large Banana 37 mg
Cooked Spinach (Leafy Greens) 180 grams (1 Cup) 157 mg
Cooked Broccoli 1 Cup 51 mg
Cooked Shelled Edamame 1 Cup 100 mg

Abundance of Magnesium

AMagnesium is the 8th most abundant element in the Earth’s crust,and the 3rd most abundance element dissolved in seawater, but it doesn’t found free in nature.

It is found in more than 60 minerals, but Magnesite, Dolomite, Carnallite, forsterite, Talc, and Olovine are of commercial importance, however, the mangnesium is largely deposits in magnesite and dolomite.
The sea contains Trillions of tones (0.13%) of magnesium, and each year produced 15,50,000 tonnes from this source.

It is
prepared by reducing magnesium oxide (MgO) with silicon (Si), or by the electrolysis (chemical decomposition by electric current) of fused magnesium chloride (MgCl2) derived from wells, brines, & sea water..

Magnesite mineral

Magnesite Mineral

dolomite mineral

Dolomite Mineral

Annual world wide production is around 18,000,000 tonnes
0.059% (In Universe)
12% (In Meteorites)
0.07% (In Sun)
2.9% (In Earth’s Crust)
0.13% (In Oceans)
0.027% (In Humans)

World’s Top producers of Magnesium

1) South Africa
2) China
3) Australia
4) Gabon
5) Brazil

World’s Top 3 Reserve holders of Magnesium

1) Russia
2) China
3) North Korea

Magnesium Price  
Pure (99.99%) metal price is around  $68-$70 per KG (KiloGram)

#magnesium

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