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Calcium Ca (Element 20) of Periodic Table

Calcium Ca (Element 20) of Periodic Table

20 Ca (Calcium)
Calcium has a silvery color metal, which is harder than sodium, and softer than aluminium.
It is less chemically reactive than the alkaline and other alkaline-earth metals.

It readily forms a white coating of nitride in air, which protects it from further corrosion, and it burns in air with a yellow-red flame.

The metal reacts easily with water and acids and produces hydrogen, which contains remarkable amounts of  hydrocarbides & ammonia as impurities.

Calcium element

Pure Calcium Metal Under Argon

Identity
CAS Number: CAS7440-70-2
CID Number:  CID5460341
DOT Hazard Class:  4.2
DOT Number:  1855

Basic Properties of Calcium

Appearance:  Silver, dull gray (with a pale yellow tint)
Mass Number:  40
Standard Atomic weight: 40.078  g/mol
Atomic number (Z):  20
Electrons: 20
Protons:  20
Neutrons:  20
Period:  4
Group:  2
Block:  s
Element category:  Alkaline earth metal
Electrons per shell:  K2, L8, M18, N2
Electron configuration:  1s22s22p63s23p64s2

Calcium electron configuration

Calcium Electron Configuration

Thermal Properties of Calcium

Phase:  Solid
Melting point:  1115 K (842 oC, 1548 oF)
Boiling point:   1757 K (1484 oC, 2703 oF)
Debye temperature:  230 K (-43.15 oC, -45.67 oF)
Fusion heat:  8.54 kJ/mol
Vaporization heat:  154.8 kJ/mol
Specific heat:  631 J/(kg K)
Molar heat capacity:  25.929 J/(mol.K)
Thermal expansion:  22.3 μm/(m∙K)
Thermal conductivity:  201 W/(m∙K)

Electrical properties of Calcium

Electrical conductivity:  29×106 S/m
A Electrical resistivity:  33.6 nΩ∙m
A Electrical type:  Conductor

Magnetic Properties of Calcium

A Magnetic type:  Diamagnetic
Magnetic susceptibility (xmol):  +40×10-6 cm3/mol
Volume magnetic susceptibility:  0.00002139
Mass magnetic susceptibility:  13.8×10-9 m3/kg
Molar magnetic susceptibility:  0.553×10-9 m3/mol

Physical Properties of Calcium

Density:  1.55 g/cm3 (In solid)  1.378 g/cm3 (In Liquid at M.P)
Molar volume:  0.000025857 m3/mol
Young’s modulus:  20 GPa
Shear modulus:  7.4 GPa
Mohs Hardness:  1.75
Bulk modulus:  17 GPa
Poisson ratio:  0.31
Brinell hardness:  170-416 MPa
Sound Speed:  3810 m/s

Atomic Properties of Calcium 

Oxidation states:  +1, +2
Valence Electrons:   4s2
Ion charge:  Ca2+
Ionization potential of an atom:  6.09
Ionization energies:  1st: 589.9 kJ.mol 2nd: 1145 kJ/mol 3rd: 4912.5 kJ/mol
Ionic radius:   99 pm
Atomic radius:  197 pm (empirical)
Van der Waals:  231 Pm
Covalent radius:  176±10 pm
Filling Orbital:  4s2
Crystal structure:  Face centred cubic
Lattice angles:  π/2, π/2, π/2
Lattice constant:  558.2, 558.2, 558.2 pm
Grid parameters:  a=5.580 Å
Space Group Name:  Fm_3m
Space Group Number:  225

Face Centered Cubic

Face Centered Cubic (FCC)

Reactivity of Calcium

Electronegativity:  1.00 (pauling scale)
Valence:  +2
Electron affinity:  2.37 kJ/mol

Nuclear Properties of Calcium

Half Life:  Stable (Infinity) 
Lifetime:  Stable (Infinity)
Quantum Number:  7F0
Neutron cross section (Brans):  5900
Neutron Mass Absorption:  4.7
Isotopes:   40Ca 41Ca 42Ca 43Ca 44Ca 45Ca 46Ca 47Ca 48Ca

Isotope Abundance (%) Atomic Mass g/mol Half Life (t1/2)
40Ca 96.941 39.964 Stable
41Ca Trace 1.03×105 y
42Ca 0.647 41.958 Stable
43Ca 0.135 42.959 Stable
44Ca 2.086 43.956 Stable
45Ca Syn 162.7 d
46Ce 0.004 45.955 Stable
47Ce Syn 4.5 d
48Ce 0.187 47.953 6.4×1019 y

Chemical Reactions of Calcium

The metal reacts with oxygen at room temp., and forming a thin layer of CaO, which protect the metal from further oxidation.
The metal once ignited, it burn in air, and forms a mixture of white calcium oxide (CaO) & calcium nitride (Ca3N2):
2 Ca (s) + O2 → 2 CaO (s)
3 Ca (s) + N2 (g) → Ca3N2 (s)

Reacts slowly with water, and forming calcium hydroxide & hydrogen:
Ca (s) + 2 H2O (l) → Ca(OH)2 (aq) + H2 (g)

Reacts with halogens, and forming Calcium (II) halides,where the reactions with fluorine & chlorine are exothermic, and with bromine & iodine are endothermic:
Ca (s) + F2 (g) → CaF2 (s) (Calcium (II) fluoride)
Ca (s) + Cl2 (g) → CaCl2 (s) (Calcium (II) chloride)
Ca (s) + Br2 (g) → CaBr2 (s) (Calcium (II)  bromide)
Ca (s) + I2 (g) → CaI2 (s) (Calcium (II) iodide)

Ca dissolves readily in dilute or concentrated hydrochloric acid (HCl), and forms Ca (II) ions & hydrogen gas:
Ca (s) + 2 HCl (aq) → Ca2+ (aq) + 2 Cl (aq) + H2 (g)

Production:
In reaction forms Ca2+ with bicarbonate ion (HCO3), by CO2 with water at seawater, which contain calcium carbonate::
 CaCO3 (s) + CO2 + H2O → Ca2+ + 2 HCO3  

Other Reactions:
Ca ions are precipitated by carbonate ions in netural to alkaline solution:
Ca2+ (aq) + CO32- (aq) → CaCO3 (s) [white]

ACa ions can be precipitated by strong bases:
Ca2+ (aq) + 2 OH (aq) → Ca(OH)2 (s)

Precipitated by phosphate ions in alkaline solutions:
5 Ca2+ (aq) + 3 PO43- (aq) + OH (aq) → Ca5(SO4)3OH (s) [white]

Ca ions are precipitated by sulfate ions in neutral to alkaline solutions.
Ca2+ (aq) + SO42- (aq) → CaSO4 (s) [white]

Calcium History

Naming:  Latin: calx, calcis (lime).
Discovery & first isolation:  Humphry Davy (1808) in London, England

Calcium Uses

ACalcium metal is used as a reducing agent (element or compound that donates electron to another chemical species) in preparing other metals such as uranium , thorium, zirconium etc.., and is used as a deoxidizer, desulfurizer, or decarburizer (compound used in a reaction to remove oxygen, sulfur,or carbon) for various ferrous and nonferrous alloys.

Calcium silicate also known as calcium orthosilicate (Ca2SiO4 or 2CaO.SiO2) is prepared in an electric oven from silica, lime, and reducing carbonated agents, and it is useful as a steel-deoxidizing agent.

It is also used as an alloying agent for copper, aluminium, beryllium, lead and magnesium alloys, and used as a “getter” for residual gases in vacuum tubes, etc.

Calcium compounds are widely used, where  vast deposits in limestone (calcium carbonate, CaCO3) used directly as a building stone and indirectly for cement.
When limestone is heated in kilns (furnace) it gives off carbon dioxide (CO2) gas leaving behind quicklime (Burnt lime or calcium oxide, CaO), which reacts vigorously with water, and give slaked lime (calcium hydroxide, Ca(OH)2).

Slaked lime (Ca(OH)2) is used to make cement, as a soil conditioner, and in water treatment to reduce acidity, and in the chemical industries, It is also used in steel making process to remove impurities from the molten iron ore.
When calcium hydroxide mixed with sand, it takes up carbon dioxide (CO2) from the air and hardens as lime plaster.

Gypsum is also known as calcium sulfate (CaSO4) is used by builders as a plaster and by nurses for setting bones, as ‘plaster of Paris’.

Calcium carbide (CaC2) is produces when heating up a mixture of carbon & lime at 3000 ºC in an electric oven and it is an acetylate which produces acetylene (C2H2) by hydrolysis (chemical breakdown of a compound due to reaction with water).

The pure calcium carbonate (CaC2) occurs in two crystalline forms; Calcite in hexagonal shaped, and  Aragonite in rhombohedric shaped.
It is very little soluble in water, but quite soluble if the water contains dissolved carbon dioxide (CO2), and forms calcium bicarbonate.

Calcium hypochlorite (whitening powder, Ca(ClO)2) is produced in the industry when passing chlorine through a lime solution, and has been used as a whitening agent, and as water purifier (bleaching powder, chlorine powder).  

Calcium cyanamide (Ca(CN)2) is also commercially known as nitrolime, It is the calcium salt of the cyanamide anion, where this chemical is used as fertilizer (helps plants to reach high yields).

Biological role of Calcium  

It has non-toxicity, even It is very essential in large quantities for all living things, particularly for the growth of healthy leaves, bones, teeth, and seashells.

Calcium phosphate (Ca3(PO4)2) is the main component of bone, and the average human contains about 1 KG (kilogram) of calcium.
Pregnant women and Children are encouraged to eat foods rich in calcium, such as milk and dairy products, green leafy vegetables, fish, and nuts & seeds.

From the IOM (U.S. Institute of Medicine), calcium  for people ages 9–18 years are not supposed to exceed 3,000 mg/day, for ages 19–50 not to exceed 2,500 mg/day, for ages 51 and older, not to exceed 2,000 mg/day.

Abundance of Calcium 

Calcium is the 5th most abundant metal in the Earth’s crust, and it is always found combined (merged with others) in nature.
it occurs abundantly as Limestone (calcium carbonate, CaCO3), Fluorite (calcium fluoride, CaF₂), Gypsum (calcium sulfate, CaSO4·2H2O), and Apatite (calcium chloro- or fluoro-phosphate, Ca5(PO4)3(F,Cl,OH)).

Hard water contains dissolved calcium bicarbonate (Ca(HCO3)2), and when this filters through the ground and reaches a cave, it precipitates out to form stalactites (icicle-shaped mineral deposit formation that hangs from the ceiling of a cave) and stalagmites (rock formation that rises from the floor of a cave).
Commercially, the metal is prepared by heating Lime with Aluminum in a vacuum.

Annual world wide production is around 50,000-70,000 tons.
0.007% (In Universe)
1.1% (In Meteorites)
0.007% (In Sun)
5% (In Earth’s Crust)
0.00042% (In Oceans)
1.4%(In Humans)

limestone

Limestone Sedimentary Rock with composed of Mineral Calcite and Aragonite

fluorite

Fluorite Crystal

gypsum

Gypsum Crystal

Apatite

Apatite Stones

World’s Top 3 producers of Calcium

1) China
2) USA
3) INDIA

Calcium Price  
Highly Pure (99.9%) metal price is around  $7000-$8000 per KG (Kilogram) and Isotope (Calcium-48) Price is $250,000 per gram.

#Calcium

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